A textbook of inorganic chemistry vol.XI part II

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26. 38 J. H. Fendler, Origin of the genetic code: a physical-chemical model of primitive codon assignments, Origins of Life 5: 357-362 (1974). W. Deamer, Role of amphiphilic compounds in the evolution of membrane structure on the early earth, Origins of Life 17: 3-25 (1986). H. Yanagawa, Y. Ogawa, K. Kojima, and M. Ito, Construction of protocellular structures under simulated primitive earth conditions, Origins Life'Evol. Biosphere 18: 179-207 (1988). G. von Kiedrowski, Ein selbstreplizierendes Hexadesoxynucleotid, Angew.

M. Bloor and E. , Kluwer, Dordrecht (1990). 29. A. C. DeSchryver, Fluorescence quenching in inverse micellar systems: possibilities and limitations, Langmuir 3 : 494-500 (1987). 30. DJ. Phillies, Quasielastic light scattering, Anal. Chem. 62: 1049A-1057A (1990). 31. M. -F. Eicke, Inverted micelles and microemulsions in the ternary system Hp/aerosol-OT/isooctane as studied by photon correlation spectroscopy, J. Phys. Chem. 83: 480-486 (1979). 32. P. L. Luisi, A continuous assay for lipases in reverse micelles based on Fourier transform infrared spectroscopy, Biochemistry 28: 3353-3360 (1989).

N•• 1,. · MnO; ~. · MnO; Fig. 8. Schematic representation of a St'lf-replicating aqueous micellar system which is based on the oxidation of octanol21 • The chemical reaction is the same as that of Fig. 5. R- and R'- as in Fig. 1. 64 M sodium permanganate, the concentration of micelles increases after 20 hours at room temperature from 14 mM to 20 mM, as again determined by time-resolved fluorescence quenching, after removal of insoluble Mn0221 • Formation of Micelles and Their Self-Replication based on Ester Hydrolysis In all the experiments described so far, the replicating units - aqueous or reverse micelles - were initially already present.

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